Қазақ ұлттық қыздар педагогикалық университеті / Казахский национальный женский педагогический университет

Постоянный URI для этого сообществаhttps://cris.qyzpu.kz/handle/123456789/1

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Тема: search.filters.subject.biochar

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    Тип записи:Публикация,
    OBTAINING BIOCHAR FROM RICE HUSK AND STRAW
    (National Academy of Sciences of the Republic of Kazakhstan, 2021-02-01)
    Nurbol Orynbasaruly Appazov
    ;
    Б.М. Базарбаев
    ;
    T. Assylbekkyzy
    ;
    Banu Diyarova
    ;
    С.А. Канжар
    This paper presents the results of research on obtaining biochar from agricultural plant waste such as rice husk and straw. The selection of the optimal conditions for thermolysis, such as the duration and temperature of the process, has been conducted. The thermolysis products are characterized for iodine adsorption activity, cumulative water pore volume, and for bulk density. The porous structure of the obtained products has been studied by scanning electron microscopy. Based on the results of the research conducted, it has been found that biochars obtained from husk and straw with a thermolysis duration of 30 minutes have low iodine sorption characteristics and water pore volumes. With an increase in the duration of thermolysis, the sorption characteristics improve, the optimal for the husk is the thermolysis duration of 60 minutes at a temperature of 500°C, and for straw, the optimal thermolysis duration is 60 minutes at a temperature of 300°C. The best option is biochar obtained from rice straw at a duration of 60 minutes and a thermolysis temperature of 300°C, having an iodine adsorption activity of 54.61%, a cumulative water pore volume of 0.941 cm3/g and a bulk density of 169.29 g/dm3. The obtained biochars from rice husk and straw have been studied by scanning electron microscopy at 4300 and 5000 times magnification, and they have a developed porous structure. According to the literature, it is known that biochar can also be used as a renewable energy source. Research has been carried out to determine the calorific value of the obtained biochars. To compare the calorific value of rice husk, straw and the obtained biochars, their heating values have been determined on a calorimeter. The highest heating value has a biochar obtained from husk at a duration of 60 minutes and at a thermolysis temperature of 400°C with a value of 17.520 kJ/g, the optimal for biochar obtained from straw is a duration of 60 minutes and a thermolysis temperature of 400°C with a value of 16.451 kJ/g. The experimental data obtained make it possible to use the obtained biochar from rice straw in the future as a biofertilizer to improve the characteristics of soils, as well as to use biochar obtained from rice husk to produce renewable fuel.
    Цитирования (OpenAlex) 19Цитирования (OpenCitations) 2
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    Тип записи:Публикация,
    Preparation of Granular Organic Iodine and Selenium Complex Fertilizer Based on Biochar for Biofortification of Parsley
    (Hindawi Publishing Corporation, 2024-01-01)
    Yerlan Doszhanov
    ;
    Meiram K. Atamanov
    ;
    Jakpar Jandosov
    ;
    Karina Saurykova
    ;
    Zhandos Bassygarayev
    This study investigates the potential of biochar derived from various biomass sources: apricot kernel (AK), pine sawdust (PS), rice husk (RH), wheat straw (WS), and reed stem (RS) to enhance the yield, nutritional quality, and environmental sustainability of parsley crops. Comprehensive characterization through SEM, EDAX, nitrogen adsorption–desorption isotherms, and FTIR analyses identified AK biochar as the most suitable for further enrichment due to its superior specific surface area (512.3 m2/g) and iodine number (51.23 mg/g). EDAX analysis revealed that AK biochar exhibited the highest carbon content (92.1%), while RH biochar contained the highest silicon content (46%), indicating different potential applications. FTIR analysis identified key functional groups, such as carbonyl (1740 cm⁻1) and hydroxyl (3430 cm⁻1) groups, which contribute to the biochar’s reactivity and potential effectiveness in various applications. The effects of selenium (Na2SeO4), iodine (KI), their combination (Na2SeO4 + KI), and BISF (biochar‐enriched iodine and selenium fertilizer) on parsley growth, antioxidant properties, and nutrient accumulation were evaluated. The results demonstrated that joint applications of iodide and selenate led to a 3.1‐fold increase in iodine content (up to 16.8 mg/kg d.w.) and a 1.2‐fold increase in selenium accumulation (up to 2482.1 μg/kg d.w.) in parsley compared to separate treatments. Additionally, BISF treatment significantly improved key biometric parameters, with leaf weight increasing by 1.6 times (up to 326.5 g) compared to the control, and antioxidant content—ascorbic acid, polyphenols, and antioxidant activity—showing increases of 1.56, 1.27, and 1.50 times, respectively. This study underscores the effectiveness of selenium‐ and iodine‐enriched biochar in enhancing parsley crop yield and nutritional quality while also demonstrating the multifunctional role of biochar in environmental remediation.
    Цитирования (OpenAlex) 6Цитирования (OpenCitations) 3
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    Eucalyptus wood waste biochar: a green solution for fluoranthene contamination in wastewater
    (Taylor & Francis, 2025-04-03)
    Yu Shuang Ren
    ;
    Bekzat Tynybekov
    ;
    Akmaral Nurmahanova
    ;
    Talgat Ibragimov
    ;
    Ussen Kurmanbay
    This study investigates the removal of fluoranthene (Flu) from vehicle-wash wastewater (VWW) using biochar (EWB) derived from eucalyptus wood waste. Analytical techniques such as surface area analysis (SAA), scanning electron microscopy (SEM), and fourier transform infrared spectroscopy (FT-IR) were employed to characterize the EWB. Optimal conditions for Flu adsorption (98.80%) were determined as 40 ppm initial concentration, 60 minutes contact time, pH 5, 60°C, and 0.4 g adsorbent dosage. The adsorption process was evaluated using kinetic models and isotherms, showing that Flu adsorption onto EWB follows a pseudo-second order kinetic model. The Langmuir isotherm provided the best fit for the experimental data. Thermodynamic analysis revealed that the adsorption process is exothermic and spontaneous, as indicated by the values of entropy (ΔS°), Gibbs free energy (ΔG°), and enthalpy (ΔH°). A comparative analysis with commercial adsorbents demonstrated the high efficacy of EWB in removing Flu from industrial wastewater, achieving over 98% efficiency.
    Цитирования (OpenAlex) 3Цитирования (OpenCitations) 2
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    1-Carboxy-2-phenylethan-1-aminium Iodide 2-Azaniumyl-3-phenylpropanoate Crystals: Properties and Its Biochar-Based Application for Iodine Enrichment of Parsley
    (Multidisciplinary Digital Publishing Institute, 2025-10-06)
    Aitugan Sabitov
    ;
    Seitzhan Turganbay
    ;
    Almagul Kerimkulova
    ;
    Yerlan Doszhanov
    ;
    Karina Saurykova
    Iodine deficiency remains a significant nutritional problem, which stimulates the search for sustainable approaches to biofortification of vegetable crops. The aim of the work was to develop a "smart" bio-iodine fertilizer based on the organoiodide complex 1-carboxy-2-phenylethan-1-aminium iodide 2-azaniumyl-3-phenylpropanoate (PPI) and highly porous biochar from agro-waste, assessing its efficiency on the parsley model. PPI was synthesized and characterized (IR/UV spectroscopy, thermal analysis), biochar was obtained by KOH activation and studied by low-temperature nitrogen adsorption (S_BET) methods, as well as standard physicochemical characterization. The granulated composition PPI + biochar (BIOF) was tested in pot experiments in comparison with KI and control; The biomass of leaves and roots, iodine and organic nitrogen content, and antioxidant indices (ascorbic acid, total polyphenols, antioxidant activity) were assessed. BIOF provided a significant increase in yield and nutrition: leaf mass reached 86.55 g/plant versus 77.72 g/plant with KI and 65.04 g/plant in the control; root mass — up to 8.25 g/plant (p<0.05). Iodine content in leaves and roots increased to 11.86 and 13.23 mg/kg (d. w.), respectively, while organic nitrogen levels increased simultaneously (57.37 and 36.63 mg/kg). A significant increase in the antioxidant status was noted (ascorbic acid 36.46 mg/100 g dry weight; antioxidant activity 44.48 mg GA/g; polyphenols 23.79 mg GA/g). The presented data show that the combination of PPI with activated biochar forms an effective platform for controlled supply of iodine to plants, increasing the yield and functional qualities of products; the prospects for implementation are associated with field trials and dosage optimization.