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Humic Acid Modified Applied Palladium Catalysts for Nitro Compounds Reduction
Автор(ы)
Индира Мухаметкеримовна Джелдыбаева
Zhaksyntay K. Kairbekov
Manshuk Z. Esenalieva
Altay Zh. Kairbekov
S.M. Suimbayeva
Дата публикации
1 января 2023 г.
Тип
journal article
Журнал
ISSN
2576-988X
Аннотация
This work studies the possibility of using humic acids (HA) as a natural polymer-modifier for applied palladium catalysts.New catalysts based on palladium -HA fixed on the carrier bauxite-094 (B-094) have been synthesized and their catalytic properties in the process of reducing p-nitrodiethylaniline (PNDA) and potassium o-nitrophinolate (PtONPh) have been studied.Humic acid is a non-toxic, inexpensive, easily accessible high molecular weight polymer.Therefore, its use as a modifier polymer for applied palladium catalysts in the processes of hydrogenation of nitro compounds is very cost-effective and relevant as of today.This work presents the results of studies on different methods for the preparation of polymer metal catalysts.It has been shown that HA has stronger acid and sorption properties, greater branching and asymmetry of macromolecules.It has been established that the activity and stability of polymer-metallic complexes (PMC) based catalysts depend on the sequence of application of the active phase on the carrier.The largest specific surface area is characterized by the catalyst 1.0% Pd-HA (1.0%)/B-094, which exhibits the greatest activity and stability in the reduction reactions of PNDA and PtONPh.Considering that HA (polymer) and bauxite-094 (carrier) are materials of natural origin, the development of such catalysts is not accompanied by large economic costs, which is one of the main requirements for modern catalysts.
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