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  5. Pyrotechnic Oxidizer Chemistry: Study-Normalized Performance Comparison and Bibliometric Mapping
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Pyrotechnic Oxidizer Chemistry: Study-Normalized Performance Comparison and Bibliometric Mapping

Автор(ы)
Kaster Kamunur
Dinara Muktaly
G. S. Beisenova
Aigerim Akhinzhanova
Tolganay Atamanova
Aisulu Batkal
Meiram K. Atamanov
Дата публикации
18 августа 2026 г.
Тип
journal article
Издатель
Multidisciplinary Digital Publishing Institute
Журнал
Applied Sciences
Том
16
Выпуск
16
Первая страница
8226
Последняя страница
8226
DOI
10.3390/app16168226
ISSN
2076-3417
Аннотация
Modern pyrotechnic materials are evolving from conventional fuel–oxidizer mixtures toward function-oriented energetic systems designed for controlled ignition, light emission, gas generation, pressure output and thermal response. This review analyzes recent progress in pyrotechnic materials through oxidizer chemistry, thermal and kinetic behavior, study-normalized performance comparison and bibliometric mapping. Representative oxidizer families, including nitrates, perchlorates, chlorates, metal oxides, hybrid oxide–salt systems, high-nitrogen salts, halogen-oxo oxidizers and coordination nitrate complexes, are compared in terms of chemical role and functional output. Thermal data show that decomposition temperature, heat release and activation energy must be interpreted together, since lower activation energy can indicate either enhanced reactivity or degradation during aging. A study-normalized relative performance factor (RPF) was used to compare performance changes within individual publications. The strongest relative improvements were associated with oxide selection, particle-size reduction, hybrid oxidizer design and coupling of nanothermites with gas-generating components. Bibliometric mapping confirmed a shift toward metal-based energetic materials, nanothermites, gas generators, combustion diagnostics, color systems and pyrotechnic devices. These trends show that oxidizer chemistry, particle architecture and additive function are increasingly selected for defined pressure, gas, light or thermal outputs.
Темы

energetic materials

nitrate

perchlorate

chlorate

metal oxides

thermal decomposition...

activation energy

heat release

particle size effects...

nanothermites

gas generator

color systems

pyrotechnic devices

science mapping

Области науки (FoS)

Engineering

Mechanics of Material...

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