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Горение и Плазмохимия

ISSN
1683-3902
3078-4778
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Energetic Materials a...

Thermochemical Biomas...

Coal Combustion and S...

Combustion and Detona...

Petroleum Processing ...

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20211

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    Тип записи:Публикация,
    One-stage synthesis of 1,1-diethoxyethane from ethanol using copper-containing catalysts
    (2021-10-12)
    Manshuk Mambetova
    ;
    Kusman Dossumov
    ;
    G.E. Ergaziyeva
    ;
    Moldir Anissova
    ;
    Bedelzhan B. Baizhomartov
    The conversion of ethanol on low-percentage copper-containing catalysts at temperatures of 300 oC and 350 oC was studied. γ-Al2O3, SiO2 and HZSM-5 were studied as the carrier of the active phase. It is shown that the main direction of ethanol conversion on low percentage copper-containing catalysts is its dehydrogenation and subsequent conversion of the resulting products into 1,1-diethoxyethane. Among the studied catalysts (1 wt.% CuO/Al2O3, 1 wt.% CuO/SiO2 and 1 wt.% CuO/ HZSM-5 the most active in the production of 1,1-diethoxyethane was 1 wt.% CuO/Al2O3, modification of it with cerium oxide led to an increase in its activity in the formation of 1,1-diethoxyethane, at the reaction temperature of 350 oС, the yield of the target product was 27 vol.%. The results showed that the modification of CuO/Al2O3 leads to an increase in the catalytic activity of the sample.