Қазақ ұлттық қыздар педагогикалық университеті / Казахский национальный женский педагогический университет
Постоянный URI для этого сообществаhttps://cris.qyzpu.kz/handle/123456789/1
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- Некоторые метрики заблокированы вашиминастройками согласия
Тип записи:Публикация, The Significant Role Of Mxene’s Derivatives And Composites In Supercapcitors: A Review(2025-01-01) ;Meruyert Nazhipkyzy ;Aknur Berkinbayeva ;Muhammad Hashami; Togzhan MashanMXene derivatives and composites are becoming fresh and promising two-dimensional (2D) materials because of their unique properties, performance, and multifunctionalities.This review covers the general aspects of MXenes (family of 2D transition metal carbides, nitrides, and carbonitrides), their MAX phase (a diverse class of nanolaminate materials with intriguing properties that have received incredible global research attention because they bridge the divide separating metals and ceramics.)precursors, dissimilarities and similarities between MAX phases and MXenes, and special properties of both materials.The important focuses are made on the methods of MXene synthesis and their stability and conductivity, as well as on synthesizing new MXene composites with desired characteristics.The impacts of MXenes in energy storage systems, especially supercapacitors, are discussed based on the high specific surface area, tunable porosity, and optimized inter-layer spacing.Here, various aspects of MXene materials, including properties, synthesis, and applications, have been discussed to highlight their importance for the development of energy storage systems and material science research.Цитирования (OpenAlex) 4Цитирования (OpenCitations) 1 - Некоторые метрики заблокированы вашиминастройками согласия
Тип записи:Публикация, Mechanism of Catalytic Thermal Decomposition of Ammonium Perchlorate in the Presence of Ti3C2Tx(2025-10-17) ;Zhanibek Korkembay ;Moldir Auyelkhankyzy; ;Zulkhair Aimukhametovich MansurovV. BykovThe thermal decomposition of ammonium perchlorate (AP) proceeds via a well-established stepwise mechanism. However, its catalytic decomposition under combustion conditions is not yet fully understood. This study investigates and clarifies the catalytic decomposition pathway of AP in the presence of Ti3C2Tx, a novel two-dimensional (2D) material with unique structural properties. MXene was chosen for its exceptional conductivity, large surface area, and layered architecture, which provide active sites for redox interactions and enhance the thermal decomposition rate of AP. During combustion of AP-based solid rocket propellants, MXene acts as a catalyst, promoting more complete and rapid oxidation reactions. The combustion products were thoroughly analyzed using X-ray phase analysis, and based on the obtained data, stoichiometric equations for the potential reaction pathways were proposed. These equations highlight the formation of metal oxides and intermediate chlorinated compounds. Furthermore, a schematic model illustrating the catalytic action of Ti3C2Tx was developed, showing the interaction between AP molecules and MXene’s surface functional groups. These findings advance understanding of nanocatalyst behavior in energetic materials and offer insights for improving solid-propellant performance via MXene incorporation.Цитирования (OpenAlex) 1
