Қазақ ұлттық қыздар педагогикалық университеті / Казахский национальный женский педагогический университет
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Тип записи:Публикация, THE COMPOSITION AND STRUCTURE OF BISMUTH-DOPED DYSPROSIUM MANGANITE(2018-12-15); ;[автор не указан в источнике] ;https://orcid.org/0000-0002-9057-5443; The quality and depth of content Web of Science offers to researchers, authors, publishers, and institutions sets it apart from other research databases.The inclusion of Bulletin of NAS RK in the Emerging Sources Citation Index demonstrates our dedication to providing the most relevant and influential multidiscipline content to our community.Қазақстан Республикасы Ұлттық ғылым академиясы "ҚР ҰҒА Хабаршысы" ғылыми журналының Web of Science-тің жаңаланған нұсқасы Emerging Sources Citation Index-те индекстелуге қабылданғанын хабарлайды.Бұл индекстелу барысында Clarivate Analytics компаниясы журналды одан əрі the Science Citation Index Expanded, the Social Sciences Citation Index жəне the Arts & Humanities Citation Index-ке қабылдау мəселесін қарастыруда.Web of Science зерттеушілер, авторлар, баспашылар мен мекемелерге контент тереңдігі мен сапасын ұсынады.ҚР ҰҒА Хабаршысының Emerging Sources Citation Index-ке енуі біздің қоғамдастық үшін ең өзекті жəне беделді мультидисциплинарлы контентке адалдығымызды білдіреді.НАН РК сообщает, что научный журнал «Вестник НАН РК» был принят для индексирования в Emerging Sources Citation Index, обновленной версии Web of Science.Содержание в этом индексировании находится в стадии рассмотрения компанией Clarivate Analytics для дальнейшего принятия журнала в the Science Citation Index Expanded, the Social Sciences Citation Index и the Arts & Humanities Citation Index.Web of Science предлагает качество и глубину контента для исследователей, авторов, издателей и учреждений - Некоторые метрики заблокированы вашиминастройками согласия
Тип записи:Публикация, SYNTHESIS AND X-RAY DIFFRACTION STUDY OF THE CHROMITE-MANGANITESIn this work synthesized new chromite-manganite phases using sol-gel method and their composition was studied by X-ray method. Chromium oxide, manganese oxide, yttrium oxide, metal carbonates, citric acid and glycerin were used as starting materials. It is shown that the use of citric acid and glycerol as precipitant, giving a positive effect to monophase samples. Precipitate was subjected to homogenizing roast in the temperature range from 600 to 1100°C, reaching the level of sintering samples were controlled by the basis of X-ray diffraction profiles. All the X-ray reflection lines have been successfully indexed according to the orthorhombic perovskite structure with space group: Pbnm (62) and with the following parameters: Y(1-x)MgCr0,5Mn0,5O3,(x≈0,7) –а=5.557, b=7.515, с=5.252 A, Z = 4; Y(1-x)BaCr0,5Mn0,5O3, (x≈0,7) –а=9.102, b=5.533, с=7.330 A, Z = 4; Y(1-x)SrCr0,5Mn0,5O3, (x≈0,7) –а=7.109, b=7.436, с=6.756 A, Z = 4. References [1] Lewis N.S., Nocera D.G. Electromicrobiology: An Emerging Reality – A Review // Proc. Natl. Acad. Sci. USA. 2006. N 103. P. 15729. [2] Turner J.A. A Realizable Renewable Energy Future // Science. 1999. N 285. P. 687-689. [3] Kreuter W., Hofmann H. Electrolysis: the important energy transformer in a world of sustainable energy // Int. J. Hydrogen Energy. 1998. N 23. Р. 661-666. [4] Singhal S.C., Kendall K. High-temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications // High-Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications. Elsevier Science, Oxford, UK, 2003. ISSN 1813-1107 3 2019 [5] Chroneos A., Yildiz B., Tarancon A., Parfitt D., Kilner J.A. Prediction of solid oxide fuel cell cathode activity with first-principles descriptors // Energy Environ. Sci. 2011. N 4. Р. 3966-3970. [6] Bockris J.O’M., Otagawa T. The Electrocatalysis of Oxygen Evolution on Perovskites // Elecrochem. Soc. 1984. N 131. Р. 290-302. [7] Man I.C., Su H.-Y., Calle-Vallejo F., Hansen H.A., Martнnez J.I., Inoglu N.G., Kitchin J., Jaramillo T.F., Nшrskov J.K., Rossmeisl J. Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces // ChemCatChem. 2011. N 3. Р. 1159-1165. [8] Skinner S.J. Recent advances in Perovskite-type materials for solid oxide fuel cell cathodes // Int. J. Inorg. Mater. 2001. N 3. Р. 113-121. [9] Haile S.M. Fuel cell materials and components // Acta Mater. 2003. N 51. Р. 5981-6000. [10] Jacobson A.J. Materials for Solid Oxide Fuel Cells // Chem. Mater. 2010. N 22. Р. 660-674. [11] Suntivich J., Gasteiger H.A., Yabuuchi N., Nakanishi H., Goodenough J.B., Shao-Horn Y. Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal-air batteries // Nat. Chem. 2011. N 3. Р. 546-550. [12] Hong W.T., Risch M., Stoerzinger K.A., Grimaud A., Suntivich J., Shao-Horn Y. Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis // Energy Environ. Sci. 2015. N 8. Р. 1404-1427. [13] Shabanova N.A., Sarkisov P.D. Osnovy zol-gel tehnologii nanodispersnogo kremnezema. M.: IKTs «Akademkniga», 2004. 208 p. [14] Kasenov B.K., Kasenova Sh.B., Sagintaeva J.I. Dvoinye i troinye manganity, ferrity i khromity elochnyh, elochnozemelnyh i redkozemelnyh metallov // M., 2017. [15] Mataev M.M., Saxena S.M., Patrin G.S., Tursinova Zh.Y., Kezdikbayeva A.T., Nurbekova M.A., Baitasheva G.U. Manganite synthesis by different methods // Oriental jornal of chemistry. 2018. N 34(3). P. 1312-1316. [16] Mataev M.M., Patrin G.S., Tursinova Zh.Y., Abdraimova M.R.,Yurkin G.Yu. Synthesis and Magnetic Properties of crystals Bi2BaFe4O10 // Journal of Siberian Federal University. Mathematics & Physics. 2018. N 11(4). Р. 411-415. - Некоторые метрики заблокированы вашиминастройками согласия
Тип записи:Публикация, Synthesis, Structure, and Electrophysical and Electrochemical Properties of Novel Composite La0.9MnO3-LaFeO3(Multidisciplinary Digital Publishing Institute, 2024-12-31); ; ;Bahadır Keskin; This article presents the synthesis, electrophysical, and catalytic properties of a La0.9MnO3–LaFeO3 nanocomposite material. The nanocomposite was synthesized via the sol–gel (Pechini) method. X-ray diffraction (XRD) analysis revealed a polycrystalline, biphasic perovskite structure combining both hexagonal and cubic symmetry. The microstructure and elemental composition, examined using field emission scanning electron microscopy (FESEM), indicated an average particle size of approximately 186.9 nm. The composite exhibits semiconducting behavior within the temperature ranges of 293–323 K and 343–393 K. Developing electrocatalysts free of precious metals for the hydrogen evolution reaction (HER) is increasingly important to facilitate the production of hydrogen from renewable sources. In this study, the conductive La0.9MnO3–LaFeO3 composite was deposited on graphite and, for the first time, evaluated as an electrocatalyst for HER in acidic media. The resulting composite films were tested using linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS) in a glassy carbon electrode (GCE) setup, providing insights into their potential as effective, cost-efficient electrocatalysts.Цитирования (OpenAlex) 9Цитирования (OpenCitations) 8 - Некоторые метрики заблокированы вашиминастройками согласия
Тип записи:Публикация, FeMnO3: Synthesis, Morphology, Dielectric Properties, and Electrochemical Behavior Toward HER by LSV(Multidisciplinary Digital Publishing Institute, 2026-02-27); ; ; ;Ramachandran KrishnamoorthyBahadır KeskinThis paper presents a comprehensive investigation into the synthesis, morphological characteristics, electrical conductivity, dielectric behavior, and electrocatalytic activity of perovskite-structured iron manganite (FeMnO3), with a specific focus on its performance in the hydrogen evolution reaction (HER). FeMnO3(FMO) nanoparticles (NPs) were synthesized using a sol–gel-type Pechini method and characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), and field-emission scanning electron microscopy combined with energy-dispersive X-ray spectroscopy (FESEM-EDS). XRD analysis confirmed the formation of a crystalline structure with cubic symmetry assigned to the Ia-3 space group, with an average crystallite size of 52.47 nm. FESEM images revealed a relatively uniform morphology with an average particle diameter of 55.84 nm. The redox and oxidation states of Fe and Mn can be studied by temperature-programmed oxidation (TPO-O2) in order to understand oxygen uptake and metal oxidation processes occurring within the FMO lattice. The dielectric constant, dielectric loss, electric modulus and electrical conductivity were calculated as a function of frequency and temperature using a Novocontrol Alpha-A broadband dielectric spectrometer (Novocontrol system) coupled with the LCR-800 precision meter. The dielectric data reveal that the FMO has semiconducting behavior with dominant charge- or ionic-relaxation processes. The electrocatalytic activity toward the HER was evaluated using linear sweep voltammetry (LSV), with the working electrode modified by an FMO catalyst ink. The material exhibited significant catalytic activity within the HER potential range, and an increase in the number of cycles led to stabilized current and enhanced hydrogen evolution. These results highlight the stability of FeMnO3 for hydrogen generation.
