Қазақ ұлттық қыздар педагогикалық университеті / Казахский национальный женский педагогический университет

Постоянный URI для этого сообществаhttps://cris.qyzpu.kz/handle/123456789/1

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  • Некоторые метрики заблокированы вашими 
    Тип записи:Публикация,
    Eucalyptus wood waste biochar: a green solution for fluoranthene contamination in wastewater
    (Taylor & Francis, 2025-04-03)
    Yu Shuang Ren
    ;
    Bekzat Tynybekov
    ;
    Akmaral Nurmahanova
    ;
    Talgat Ibragimov
    ;
    Ussen Kurmanbay
    This study investigates the removal of fluoranthene (Flu) from vehicle-wash wastewater (VWW) using biochar (EWB) derived from eucalyptus wood waste. Analytical techniques such as surface area analysis (SAA), scanning electron microscopy (SEM), and fourier transform infrared spectroscopy (FT-IR) were employed to characterize the EWB. Optimal conditions for Flu adsorption (98.80%) were determined as 40 ppm initial concentration, 60 minutes contact time, pH 5, 60°C, and 0.4 g adsorbent dosage. The adsorption process was evaluated using kinetic models and isotherms, showing that Flu adsorption onto EWB follows a pseudo-second order kinetic model. The Langmuir isotherm provided the best fit for the experimental data. Thermodynamic analysis revealed that the adsorption process is exothermic and spontaneous, as indicated by the values of entropy (ΔS°), Gibbs free energy (ΔG°), and enthalpy (ΔH°). A comparative analysis with commercial adsorbents demonstrated the high efficacy of EWB in removing Flu from industrial wastewater, achieving over 98% efficiency.
    Цитирования (OpenAlex) 3Цитирования (OpenCitations) 2
  • Некоторые метрики заблокированы вашими 
    Тип записи:Публикация,
    Zeolites and Activated Carbons in Hydroponics: A Systematic Review of Mechanisms, Performance Metrics, Techno-Economic Analysis and Life-Cycle Assessment
    (Multidisciplinary Digital Publishing Institute, 2025-12-08)
    Dana Akhmetzhanova
    ;
    ;
    Yerlan Doszhanov
    ;
    ;
    Karina Saurykova
    The sustainable operation of hydroponic systems depends on maintaining the chemical stability of circulating nutrient solutions and preventing the accumulation of toxic compounds. The accumulation of phytotoxic ammonium, heavy metals, and organic metabolites in recirculating nutrient solutions remains one of the key challenges limiting the efficiency, sustainability, and scalability of hydroponic cultivation. This review provides a comprehensive comparative analysis of zeolites, activated carbons (ACs), and their functionalized and composite forms as key sorbents for nutrient management, contaminant removal, and environmental safety in hydroponic cultivation. Natural zeolites, with their well-defined crystalline structure and high ion-exchange selectivity toward ammonium and heavy metal cations, enable effective NH4+/K+ balance regulation and phytotoxicity mitigation. ACs, characterized by high specific surface area and tunable surface chemistry, complement zeolites by offering extensive adsorption capacity for organic compounds, root exudates, and pesticide residues, thereby extending the operational lifespan of nutrient solutions and improving overall system performance. Further advancements include the integration of zeolites and ACs with two-dimensional (graphene, g-C3N4) and three-dimensional (MOF, COF) frameworks, yielding multifunctional materials that combine adsorption, ion exchange, photocatalysis, and nutrient regulation. Transition-metal modification, particularly with Fe, Mn, Cu, Ni, and Co, introduces redox-active centers that enhance sorption, catalysis, and phosphate stabilization. The comparative synthesis reveals that the combined application of zeolite- and carbon-based composites offers a synergistic strategy for developing adaptive and low-waste hydroponic systems. From a techno-economic and environmental standpoint, the judicious application of these materials paves the way for more resilient, efficient, and circular hydroponic systems, reducing fertilizer and water consumption, lowering contaminant discharge, and enhancing food security. This systematic review was conducted according to the PRISMA 2020 guidelines. Relevant studies were identified through Scopus, Web of Science, and Google Scholar databases using specific inclusion and exclusion criteria.
    Цитирования (OpenAlex) 5Цитирования (OpenCitations) 1
  • Некоторые метрики заблокированы вашими 
    Тип записи:Публикация,
    ADSORBENTS BASED ON MODIFIED NANOCELLULOSE: WATER PURIFICATION FROM ORGANIC AND INORGANIC POLLUTANTS
    (Shakarim University, 2026-07-29)
    Zhexenbek Toktarbay
    ;
    Makhabbat Kunarbekova
    ;
    ;
    Kenes Kudaibergenov
    ;
    Dana Ashiraliyeva
    Against the backdrop of rapid industrial growth, water pollution has become a pressing global environmental issue. This review provides a systematic analysis of the efficiency of functionalized nanocellulose- based adsorbents for the removal of organic (synthetic dyes, phenols, antibiotics, pesticides) and inorganic (Pb 2+ , Cd 2+ , Hg 2+ , Cr(VI), Cu 2+ , As) pollutants from water. Key findings: the highest sorption capacities are achieved by TEMPO-oxidized nanocellulose and amine-functionalized composites – up to 2500 mg/g for methylene blue and up to 2270 mg/g for lead ions. Nanocellulose-based molecularly imprinted polymers (MIPs) selectively adsorb phenols with efficiencies of up to 97% even in the presence of structurally similar competitors. Most adsorbents reviewed retain 80+90% of their capacity after 20 regeneration cycles. The paper examines three main types of nanocellulose (CNC, NFC, BNC), their preparation methods (acid hydrolysis, TEMPO-oxidation, mechanical and enzymatic treatment), and surface functionalization strategies (isocyanate-based, amine- and thiol-functionalization). The alignment of nanocellulose production from agricultural waste (rice husks, soybean hulls) with sustainable development principles is emphasized. Key unresolved challenges – scale-up, stability in real wastewater matrices, and cost-effectiveness – and future research directions are also identified.