Қазақ ұлттық қыздар педагогикалық университеті / Казахский национальный женский педагогический университет

Постоянный URI для этого сообществаhttps://cris.qyzpu.kz/handle/123456789/1

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  • Некоторые метрики заблокированы вашими 
    Тип записи:Публикация,
    Биошикізат негізіндегі кеуекті көміртекті сорбциялық материалдар алу және физика-химиялық қасиеттерін зерттеу
    (2026-04-06)
    А.Р. Керимкулова
    ;
    Е.Ж. Ермолданов
    ;
    Н.М. Асанбек
    ;
    ;
    А.Н. Жумагалиева
    For the first time, an approach to the production of highly efficient porous carbon sorption materials based on lignocellulose agricultural waste has been developed and a comprehensive assessment of their physico-chemical properties has been carried out. Rice husks (RH), walnut shells (WSh), wheat straw (WSt) and pine sawdust (PS) were used as raw materials. The resulting carbonysates were chemically activated with potassium hydroxide at different mass ratios of the activating agent and the carbon matrix. To increase the surface chemical activity of sorbents, potassium hydroxide was used. The morphology of the surface and the elemental composition of the synthesized materials were studied using scanning electron microscopy and energy dispersion analysis, and the functional groups were studied using Fourier transform infrared spectroscopy (FTIR). It has been established that an increase in the degree of activation leads to the development of a hierarchical porous structure with the formation of micro-, meso- and macropores, as well as to an increase in the content of oxygen- and nitrogen-containing functional groups on the surface of carbon materials. The greatest microporosity was achieved with a KOH:carbon mass ratio of 1:4. The formed functional structure helps to increase the sorption capacity of materials in relation to toxic pollutants of various nature. The results obtained confirm the prospects of using synthesized carbon sorbents as environmentally safe and economically feasible materials for cleaning air and water environments.
  • Некоторые метрики заблокированы вашими 
    Тип записи:Публикация,
    Use of Urea-Modified Activated Carbon Sorbents Derived from Plant Residues for Gas Sorption
    (Multidisciplinary Digital Publishing Institute, 2026-07-07)
    Almagul Kerimkulova
    ;
    Yersultan Yermoldanov
    ;
    ;
    Leticia Fernández Velasco
    ;
    Nazym Asanbek
    The growing demand for efficient and sustainable materials for air purification has stimulated interest in activated carbons derived from renewable biomass resources. In this study, activated carbons were prepared from rice husk, wheat straw, sawdust, and walnut shells and systematically investigated as sorbents for toxic gases and volatile organic compounds. The materials were characterized using nitrogen and water vapour sorption isotherms, scanning electron microscopy, thermogravimetric analysis, Fourier-transform infrared spectroscopy, and energy-dispersive X-ray analysis to evaluate their textural properties, morphology, thermal stability, and surface chemistry. The results showed that the precursor type strongly influences the pore structure and functional group composition of the activated carbons. Wheat straw and Rice husk–derived activated carbons exhibited the highest total pore volume and a well-developed porous structure, together with a high content of oxygen- and silicon-containing elements. Gas breakthrough experiments with different probes showed that wheat straw–derived activated carbon excels in VOC removal due to its highly microporous structure. In contrast, rice husk–derived activated carbon displays strong affinity toward inorganic gases such as NH₃ and, after urea modification, achieves enhanced performance for SO₂. These results underscore the versatility and practical applicability of carbon materials obtained from plant residues.