Жарияланымдар / Публикации

Постоянный URI для этого сообществаhttps://cris.qyzpu.kz/handle/123456789/2

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  • Некоторые метрики заблокированы вашими 
    Тип записи:Публикация,
    Биошикізат негізіндегі кеуекті көміртекті сорбциялық материалдар алу және физика-химиялық қасиеттерін зерттеу
    (2026-04-06)
    А.Р. Керимкулова
    ;
    Е.Ж. Ермолданов
    ;
    Н.М. Асанбек
    ;
    ;
    А.Н. Жумагалиева
    For the first time, an approach to the production of highly efficient porous carbon sorption materials based on lignocellulose agricultural waste has been developed and a comprehensive assessment of their physico-chemical properties has been carried out. Rice husks (RH), walnut shells (WSh), wheat straw (WSt) and pine sawdust (PS) were used as raw materials. The resulting carbonysates were chemically activated with potassium hydroxide at different mass ratios of the activating agent and the carbon matrix. To increase the surface chemical activity of sorbents, potassium hydroxide was used. The morphology of the surface and the elemental composition of the synthesized materials were studied using scanning electron microscopy and energy dispersion analysis, and the functional groups were studied using Fourier transform infrared spectroscopy (FTIR). It has been established that an increase in the degree of activation leads to the development of a hierarchical porous structure with the formation of micro-, meso- and macropores, as well as to an increase in the content of oxygen- and nitrogen-containing functional groups on the surface of carbon materials. The greatest microporosity was achieved with a KOH:carbon mass ratio of 1:4. The formed functional structure helps to increase the sorption capacity of materials in relation to toxic pollutants of various nature. The results obtained confirm the prospects of using synthesized carbon sorbents as environmentally safe and economically feasible materials for cleaning air and water environments.
  • Некоторые метрики заблокированы вашими 
    Тип записи:Публикация,
    ADSORBENTS BASED ON MODIFIED NANOCELLULOSE: WATER PURIFICATION FROM ORGANIC AND INORGANIC POLLUTANTS
    (Shakarim University, 2026-07-29)
    Zhexenbek Toktarbay
    ;
    Makhabbat Kunarbekova
    ;
    ;
    Kenes Kudaibergenov
    ;
    Dana Ashiraliyeva
    Against the backdrop of rapid industrial growth, water pollution has become a pressing global environmental issue. This review provides a systematic analysis of the efficiency of functionalized nanocellulose- based adsorbents for the removal of organic (synthetic dyes, phenols, antibiotics, pesticides) and inorganic (Pb 2+ , Cd 2+ , Hg 2+ , Cr(VI), Cu 2+ , As) pollutants from water. Key findings: the highest sorption capacities are achieved by TEMPO-oxidized nanocellulose and amine-functionalized composites – up to 2500 mg/g for methylene blue and up to 2270 mg/g for lead ions. Nanocellulose-based molecularly imprinted polymers (MIPs) selectively adsorb phenols with efficiencies of up to 97% even in the presence of structurally similar competitors. Most adsorbents reviewed retain 80+90% of their capacity after 20 regeneration cycles. The paper examines three main types of nanocellulose (CNC, NFC, BNC), their preparation methods (acid hydrolysis, TEMPO-oxidation, mechanical and enzymatic treatment), and surface functionalization strategies (isocyanate-based, amine- and thiol-functionalization). The alignment of nanocellulose production from agricultural waste (rice husks, soybean hulls) with sustainable development principles is emphasized. Key unresolved challenges – scale-up, stability in real wastewater matrices, and cost-effectiveness – and future research directions are also identified.