Жарияланымдар / Публикации
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- Некоторые метрики заблокированы вашиминастройками согласия
Тип записи:Публикация, ПОЛУЧЕНИЕ АКТИВИРОВАННОГО УГЛЯ СО-ТЕРМОЛИЗОМ РИСОВОЙ СОЛОМЫ И НЕФТЕШЛАМА(2019-01-01) ;Nurbol Orynbasaruly Appazov ;R. A. Turmanov ;Rakhmetulla Zhapparbergenov ;A. T. ShuragaziyevaNurgali AkylbekovCarrying out joint activities in order to obtain a widely used adsorbent – activated carbon. A carbonization tube in a tube furnace made of stainless steel at a temperature of 500°C, and activation of a carbonizate carried out by steam at a temperature of 800°C. The influence of the ratio of the initial components of the raw material (husk:oil sludge) on the properties of the product was studied. Husk:oil sludge is 9:1 (by weight), respectively. Indicators such as water adsorption activity, total owner volume and bulk figure were studied. The microstructure of the obtained activated carbon was studied on a scanning electron microscope. 9: 1 corresponds to activated carbon brand DAK. References [1] Kinle H., Bader Je. Aktivnye ugli i ih promyshlennoe primenenie. L.: Himija, 1984. 216 p. [2] Arezou Niksiar, Bahram Nasernejad. Activated carbon preparation from pistachio shell pyrolysis and gasification in a spouted bed reactor // Biomass and Bioenergy. 2017. Vol. 106. P. 43-50. DOI: 10.1016/j.biombioe.2017.08.017. [3] Yeru Liang, Chen Yang, Hanwu Dong, Wenqi Li, Hang Hu, Yong Xiao, Mingtao Zheng, Yingliang Liu. Facile Synthesis of Highly Porous Carbon from Rice Husk // ACS Sustainable Chem. Eng., Just Accepted Manuscript. 2017. Vol. 5, N. 8. P. 7111-7117. DOI: 10.1021/acssuschemeng.7b01315. [4] Wenli Zhang, Nan Lin, Debo Liu, Jinhui Xu, Jinxin Sha, Jian Yin, Xiaobo Tan, Huiping Yang, Haiyan Lu, Haibo Lin. Direct carbonization of rice husk to prepare porous carbon for supercapacitor applications // Energy. 2017. Vol. 128. P. 618-625. DOI: 10.1016/j.energy.2017.04.065. [5] Pred.patent RK №15933. Sposob poluchenija karbonizirovannogo sorbenta dlja izvlechenija zolota iz rastvorov / Mansurov Z.A., Mansurova R.M., Nikolaeva A.F., Vasil'ev D.G.; data opubl. 15.07.2005. Bjul. №7. [6] Patent RF №2315712 na izobretenie. Sposob poluchenija aktivirovannogo uglja iz othodov sel'skogo hozjajstva / Hoang Kim Bong, Timofeev V.S., Tjomkin O.N., Gafarov I.G., Timoshenko A.V., Artamonova T.V., Gorbacheva O.V., Kol'vah I.P., Mishulin G.M., Shhepakin M.B., Kozhura E.A., Haziev R.M., Vatolin A.K.; data opubl. 27.01.2008. [7] Patent RF №2527221 na izobretenie. Sposob poluchenija aktivnogo uglja iz rastitel'nyh othodov / Muhin V.M., Voropaeva N.L., Karpachev V.V., Harlamov S.A., Spiridonov Ju.Ja., Gur'janov V.V., Dmitrjakova E.E.; data opubl. 27.08.2014. [8] Aworn A. Preparation of CO2 activated carbon from corncob for monoethylene glycol adsorption / A. Amphol, T. Paitip, N. Woranan // Colloids and Surfaces A: Physicochem and Eng. Asp. 2009. Vol. 333. Is. 1-3. P. 19-25. [9] Chang Ch-F. Effects of Burn-off and Activation Temperature on Preparation of Activated Carbon from Corn Cob Agrowaste by CO2 and Steam / Ch-F. Chang, Ch-Y. Chang, W-T. Tsai // Journal of Colloid and Interface Science. 2000. Vol. 232, N 1. P. 45-49. [10] Hanum F., Bani O., Wirani L.I. Characterization of Activated Carbon from Rice Husk by HCl Activation and Its Application for Lead (Pb) Removal in Car Battery Wastewater // IOP Conf. Series: Materials Science and Engineering. 2017. Vol. 180, 012151. DOI: 10.1088/1757899X/180/1/012151. [11] Hanum F., Bani O., Izdiharo A.M. Characterization of Sodium Carbonate (Na2CO3) Treated Rice Husk Activated Carbon and Adsorption of Lead from Car Battery Wastewater // IOP Conf. Series: Materials Science and Engineering. 2017. Vol. 180, 012149. DOI: 10.1088/1757899X/180/1/012149. [12] Patent RF №2609802 na izobretenie. Sposob poluchenija aktivnogo uglja iz rastitel'nogo syr'ja / Klushin V.N., Thu Aung Si, Muhin V.M., Vin M'int So, Nistratov A.V., Voropaeva N.L.; data opubl. 06.02.2017. Bjul. №4. [13] Daifullah A.A.M., Girgis B.S., Gad H.M.H. A study of the factors affecting the removal of humic acid by activated carbon prepared from biomass material // Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2004. Vol. 235, N 1-3. P. 1-10. DOI: 10.1016/j.colsurfa.2003.12.020. [14] Mohamed M.M. Acid dye removal: comparison of surfactant-modified mesoporous FSM-16 with activated carbon derived from rice husk // Journal of Colloid and Interface Science. 2004. Vol. 272, N 1. P. 28-34. DOI: 10.1016/j.jcis.2003.08.071. [15] Rahman I.A. Saad B., Shaidan S., Sya Rizal E.S. Adsorption characteristics of malachite green on activated carbon derived from rice husks produced by chemical–thermal process // Bioresource Technology. 2005. Vol. 96, N 14. P. 1578-1583. DOI: 10.1016/j.biortech.2004.12.015. [16] Kennedy L.J., Vijaya J.J., Sekaran G. Effect of Two-Stage Process on the Preparation and Characterization of Porous Carbon Composite from Rice Husk by Phosphoric Acid Activation // Ind. Eng. Chem. Res. 2004. Vol. 43, N 8. P. 1832-1838. DOI: 10.1021/ie034093f. [17] Guo Y. Rockstraw D.A. Activated carbons prepared from rice hull by one-step phosphoric acid activation // Microporous and Mesoporous Materials. – 2007. Vol. 100. Is. 1-3. P. 12-19. DOI: 10.1016/j.micromeso.2006.10.006. [18] GOST 6217. Ugol' aktivnyj drevesnyj droblenyj. Tehnicheskie uslovija. M.: IPK Izdatel'stvo standartov, 2003. [19] GOST 17219. Ugli aktivnye. Metod opredelenija summarnogo ob#ema por po vode. M.: Izdatel'stvo standartov, 1988. [20] GOST 12597. Sorbenty. Metod opredelenija massovoj doli vody v aktivnyh ugljah i katalizatorah na ih osnove. M.: Izdatel'stvo standartov, 1989. [21] GOST 16190. Sorbenty. Metod opredelenija nasypnoj plotnosti. M.: Izdatel'stvo standartov, 1970. - Некоторые метрики заблокированы вашиминастройками согласия
Тип записи:Публикация, OBTAINING BIOCHAR FROM RICE HUSK AND STRAW(National Academy of Sciences of the Republic of Kazakhstan, 2021-02-01) ;Nurbol Orynbasaruly Appazov ;Б.М. Базарбаев ;T. Assylbekkyzy; С.А. КанжарThis paper presents the results of research on obtaining biochar from agricultural plant waste such as rice husk and straw. The selection of the optimal conditions for thermolysis, such as the duration and temperature of the process, has been conducted. The thermolysis products are characterized for iodine adsorption activity, cumulative water pore volume, and for bulk density. The porous structure of the obtained products has been studied by scanning electron microscopy. Based on the results of the research conducted, it has been found that biochars obtained from husk and straw with a thermolysis duration of 30 minutes have low iodine sorption characteristics and water pore volumes. With an increase in the duration of thermolysis, the sorption characteristics improve, the optimal for the husk is the thermolysis duration of 60 minutes at a temperature of 500°C, and for straw, the optimal thermolysis duration is 60 minutes at a temperature of 300°C. The best option is biochar obtained from rice straw at a duration of 60 minutes and a thermolysis temperature of 300°C, having an iodine adsorption activity of 54.61%, a cumulative water pore volume of 0.941 cm3/g and a bulk density of 169.29 g/dm3. The obtained biochars from rice husk and straw have been studied by scanning electron microscopy at 4300 and 5000 times magnification, and they have a developed porous structure. According to the literature, it is known that biochar can also be used as a renewable energy source. Research has been carried out to determine the calorific value of the obtained biochars. To compare the calorific value of rice husk, straw and the obtained biochars, their heating values have been determined on a calorimeter. The highest heating value has a biochar obtained from husk at a duration of 60 minutes and at a thermolysis temperature of 400°C with a value of 17.520 kJ/g, the optimal for biochar obtained from straw is a duration of 60 minutes and a thermolysis temperature of 400°C with a value of 16.451 kJ/g. The experimental data obtained make it possible to use the obtained biochar from rice straw in the future as a biofertilizer to improve the characteristics of soils, as well as to use biochar obtained from rice husk to produce renewable fuel.Цитирования (OpenAlex) 19Цитирования (OpenCitations) 2
