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Автор: search.filters.author.О. V. SuberlyakЯзык: search.filters.language.Қазақ тілі

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    КАТИОНИТ КУ-2-8 ЖӘНЕ АНИОНИТ АВ-17 ГИДРОГЕЛЬДЕРІНЕН ТҰРАТЫН ИНТЕРГЕЛЬДІ ЖҮЙЕНІҢ ӨЗАРА АКТИВТЕЛУ ЕРЕКШЕЛІКТЕРІ
    (2020-01-01)
    Talkybek Jumadilov
    ;
    Zamira Malimbayeva
    ;
    О. V. Suberlyak
    ;
    И. С. Сапарбекова
    The mutual activation of polymer meshes in the intergel system was studied in order to identify the absorbing abilities and selectivity of hydrogels. An intergel system consisting of KU-2-8 cationite (swell) and AB-17 anionite (swell) was chosen as the object of research. it was Found that as a result of the remote action of hydrogels, mutual activity occurs, leading to significant differences in their electrochemical and conformational composition. References [1] Bekturov E.A., Dzhumadilov T.K. Novye podhody k izucheniyu effekta distancionnogo vzaimovliyaniya gidrogelej // Izv. NAN RK. Ser. him. 2009. N 1. P. 86-87. [2] BekturovE.A., DzhumadilovT.K., KorganbaevaZH.K. Distancionnyj effekt v polimernyh sistemah // Vestnik KazNU. Ser. him. 2010. N 3. P. 108-110. [3] Jumadilov T., Shaltykova D., Suleimenov I. Anomalousion exchange phenomenon // Proceedings of the Austrian-slovenian polymer meeting (ASPM 2013). – Slovenia, 2013. – P. 51. [4] Jumadilov T., Kaldayeva S., Kondaurov R., Erzhan B., Erzhet B. Mutual activation and high selectivity of polymeric structures in intergel systems / Jumadilov T. // High performance polymers for engineering based composites / Omari V. Mukbaniani, Marc J.M. Abadie,TamaraTatrishvilli. CRCpress, 2015. P. 111-119. [5] Jumadilov T.K. Electrochemical and conformation albehaviour of intergel systems based on the rare crosslinked polyacid and polyvynil pyrydines // Proceeding of the international conference of Lithuanian Chemical Society – Chemistry and Chemical Technology. Kaunas, Lithuania, 2014. P. 226-229. [6] Dzhumadilov T.K. Effekt distancionnogo vzaimodejstviya polimernyh gidrogelej v innovacionnoj tekhnologii // Promyshlennost' Kazahstana. 2011. N 2. P. 70-72. [7] Jumadilov T.K. Hydrogels remote interaction–basis of new phenomena and technologies // 10th Polyimides & High Performance Polymers Conference. Montpellier, France, june 2016. P. CIV-7. [8] Alimbekova B.T., Korganbayeva Zh.K., Himersen H., Kondaurov R.G. and Jumadilov T.K. // J. Chem. Chem. Eng. 2014. Vol. 8, N 3. P. 265-269. [9] Dzhumadilov T.K., Abilov Zh.A., Kondaurov R.G.. Vliyanie vzaimnoj aktivacii gidrogelej polimetakrilovoj kisloty i poli-2-metil-5-vinilpiridina na sorbcionnuyu sposobnost' intergelevoj sistemy po otnosheniyu k ionam lantana // Himicheskij zhurnal Kazahstana. 2014. N 4. P. 128-135. [10] Jumadilov T.K., Kaldayeva S.S., Kondaurov R.G., Erzhan B., Erzhet B. // Proceedings of symposium ICSP&AM3. Tbilisi, 2013. P. 191-196.
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    НЕОДИМ ИОНДАРЫН СІҢІРУГЕ АРНАЛҒАН МОЛЕКУЛАЛЫҚ ТАҢБАЛЫ ПОЛИМЕРЛЕР СИНТЕЗІ
    (2020-01-01)
    О. V. Suberlyak
    ;
    Talkybek Jumadilov
    ;
    Zamira Malimbayeva
    ;
    И. С. Сапарбекова
    In order to develop a selective technology for obtaining metal ions from water systems, molecular imprinted polymers (MIP) were synthesized and studied. In the course of the study, template MIPs Nd3+ (secondary polymer mesh) and pseudomatrix without a template (primary polymer mesh) were synthesized. The MIP obtained with the misprint of the neodymium (III) ion was obtained from two functional monomers of methacrylic acid and 4-vinylpyridine. Complex formation with matrix neodymium ions in the ionic interaction of two functional monomers is studied. References [1] Dzhumadilov T.K. Kondaurov R.G. Polimery s molekulyarnymi otpechatkami – osnova budushchih tekhnologij:monografiya. Almaty, 2017. P. 5-14.[2] Takagishi T., Klotz I.M. Macromolecule-small molecule interactions; introduction of additional binding sites in polyethyleneimine by disulfide cross-linkages // Biopolymers. 1972. № 11(2). P. 483-491. DOI:10.1002 /bip.1972.360110213[3] Shakerian F., Dadfarnia S., A.M. Haji Shabani Synthesis and characterization of nano-pore antimony imprinted polymer and its use in the extraction and determination of antimony in water and fruit juice samples // Food Chem. 2014. № 145 P. 571-577. DOI:10.1016/j.foodchem.2013.08.110[4] Branger, C., Meouche, W., & Margaillan, A. Recent advances on ion-imprinted polymers // Reactive and Functional Polymers. 2013. № 73(6). P. 859-875. DOI:10.1016/j.reactfunctpolym.2013.03.021[5] Dzhumadilov T.K., Imangazy A.M., Kondaurov R.G., Himersen H. Razrabotka tekhnologii selektivnoj sorbcii ionov metallov polimerami s «molekulyarnymi otpechatkami» // 84-ya nauchno-tekhnicheskaya konferenciya professorsko-prepodavatel'skogo sostava, nauchnyh sotrudnikov i aspirantov (s mezhdunarodnym uchastiem) (Minsk, 3-4 fevralya 2020 g.). Minsk: Izdatel'stvo Belorusskogo gosudarstvennogo tekhnologicheskogo universiteta, 2020.[6] http://chem.msu.ru/rus/teaching/eremin/10.html Uchebnye materialy po fizicheskoj himii. Zadachi po fizicheskoj himii.CHast' 2.Himicheskaya kinetika. Elektrohimiya