Жарияланымдар / Публикации
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- Некоторые метрики заблокированы вашиминастройками согласия
Тип записи:Публикация, Synthesis and Heavy-Metal Sorption Studies of N,N-Dimethylacrylamide-Based Hydrogels(Multidisciplinary Digital Publishing Institute, 2021-09-13)Цитирования (OpenAlex) 24Цитирования (OpenCitations) 19 - Некоторые метрики заблокированы вашиминастройками согласия
Тип записи:Публикация, Structural and Sorption Characteristics of Nano-Structured Polysaccharide Biopolymers Derived from Plants of the Asteraceae Family(2026-07-17); ; ; ; This study investigates the structural and sorption characteristics of nanostructured polysaccharide biopolymers isolated from plants of the Asteraceae family (Dahlia tubers and Helianthus tuberosus) toward Pb2+ ions in model aqueous solutions. The biopolymers were obtained by acid extraction at pH 1.5-2.5 and 80-90 °C, followed by ethanol precipitation, with a yield of 10-14%.Surface morphology examined by scanning electron microscopy revealed a hierarchically organized nano- and micro structured matrix with particle agglomeration and developed interaggregate porosity. The presence of lamellar structures and a porous network promotes diffusion of metal ions to active functional centers.The interaction mechanism between the biopolymer matrix and Pb2+ was studied by FTIR spectroscopy. Shifts and intensity changes of absorption bands corresponding to carboxyl and hydroxyl groups confirmed a coordination-chelate complexation mechanism without destruction of the polysaccharide backbone.Sorption experiments were performed using model Pb2+ solutions prepared from analytical-grade lead (II) acetate. The residual Pb2+ concentration after contact with the biopolymer was determined by atomic absorption spectrometry at 283.3 nm using calibration. Additional control measurements were conducted by complexometric titration in acetate buffer medium (pH 5.5) with 0.01 M Trilon B.Up to 76-77% of Pb2+ was removed within the first 10 min, and sorption equilibrium was reached after 60 min. The maximum removal efficiency reached 87%. The Freundlich model best described the process, indicating heterogeneous surface structure and multilayer adsorption. These results demonstrate the potential of Asteraceae-derived polysaccharide biopolymers as environmentally safe sorbents for heavy metal removal from aqueous media. - Некоторые метрики заблокированы вашиминастройками согласия
Тип записи:Публикация, ADSORBENTS BASED ON MODIFIED NANOCELLULOSE: WATER PURIFICATION FROM ORGANIC AND INORGANIC POLLUTANTS(Shakarim University, 2026-07-29);